Defect Engineering Activates Schottky Heterointerfaces of Graphene/CoSe2 Composites with Ultrathin and Lightweight Design Strategies to Boost Electromagnetic Wave Absorption

被引:59
|
作者
Ding, Jiawei [1 ]
Shi, Rongrong [1 ]
Gong, Chuangchuang [1 ]
Wang, Chenxu [1 ]
Guo, Yue [2 ]
Chen, Tong [1 ]
Zhang, Yijing [1 ]
Cong, Hongwei [1 ]
Shi, Chunsheng [1 ]
He, Fang [1 ]
机构
[1] Tianjin Univ, Tianjin Key Lab Composites & Funct Mat, Key Lab Adv Ceram & Machining Technol, Minist Educ,Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
[2] Tianjin Univ, Sch Microelect, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
CoSe2; nanoparticles; defect engineering; electromagnetic wave absorption; lightweight; reduced graphene oxide; Schottky heterointerfaces; ultra-thin materials; PERFORMANCE; NANOPARTICLES; ABSORBERS; AEROGELS;
D O I
10.1002/adfm.202305463
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To tackle the increasingly complex electromagnetic (EM) pollution environment, the application-oriented electromagnetic wave (EMW) absorption materials with ultra-thin, light weight and strong tolerance to harsh environment are urgently explored. Although graphene aerogel-based lightweight EMW absorbers have been developed, thinner thickness and more effective polarization loss strategies are still essential. Based on the theory of EMW transmission, this work innovatively proposes a high attenuation design strategy for obtaining ultra-thin EMW absorption materials, cobalt selenide (CoSe2) is determined as animportant part of ultra-thin absorbers. In order to obtain a dielectric parameter range that satisfies the ultra-thin absorption characteristics and improve the lightweight properties of EMW absorption materials, a composite of CoSe2 modified N-doped reduced graphene oxide (N-RGO/CoSe2) is designed. Meanwhile, the controllable introduction of defect engineering into RGO can activate Schottky heterointerfaces of composites to generate a strong interfacial polarization effect, achieving ultra-thin characteristics while significantly improving the EM loss capability. In addition, infrared thermal images and anti-icing experiments show that the composite has good corrosion resistance, infrared stealth, and thermal insulation properties. Therefore, this work provides an effective strategy for obtaining thin-thickness, light-weight, and high-performance EMW absorption materials, embodying the advantages of N-RGO/CoSe2 composites in practical applications.
引用
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页数:14
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