共 2 条
Defect Engineering Activates Schottky Heterointerfaces of Graphene/CoSe2 Composites with Ultrathin and Lightweight Design Strategies to Boost Electromagnetic Wave Absorption
被引:59
|作者:
Ding, Jiawei
[1
]
Shi, Rongrong
[1
]
Gong, Chuangchuang
[1
]
Wang, Chenxu
[1
]
Guo, Yue
[2
]
Chen, Tong
[1
]
Zhang, Yijing
[1
]
Cong, Hongwei
[1
]
Shi, Chunsheng
[1
]
He, Fang
[1
]
机构:
[1] Tianjin Univ, Tianjin Key Lab Composites & Funct Mat, Key Lab Adv Ceram & Machining Technol, Minist Educ,Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
[2] Tianjin Univ, Sch Microelect, Tianjin 300072, Peoples R China
基金:
中国国家自然科学基金;
关键词:
CoSe2;
nanoparticles;
defect engineering;
electromagnetic wave absorption;
lightweight;
reduced graphene oxide;
Schottky heterointerfaces;
ultra-thin materials;
PERFORMANCE;
NANOPARTICLES;
ABSORBERS;
AEROGELS;
D O I:
10.1002/adfm.202305463
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
To tackle the increasingly complex electromagnetic (EM) pollution environment, the application-oriented electromagnetic wave (EMW) absorption materials with ultra-thin, light weight and strong tolerance to harsh environment are urgently explored. Although graphene aerogel-based lightweight EMW absorbers have been developed, thinner thickness and more effective polarization loss strategies are still essential. Based on the theory of EMW transmission, this work innovatively proposes a high attenuation design strategy for obtaining ultra-thin EMW absorption materials, cobalt selenide (CoSe2) is determined as animportant part of ultra-thin absorbers. In order to obtain a dielectric parameter range that satisfies the ultra-thin absorption characteristics and improve the lightweight properties of EMW absorption materials, a composite of CoSe2 modified N-doped reduced graphene oxide (N-RGO/CoSe2) is designed. Meanwhile, the controllable introduction of defect engineering into RGO can activate Schottky heterointerfaces of composites to generate a strong interfacial polarization effect, achieving ultra-thin characteristics while significantly improving the EM loss capability. In addition, infrared thermal images and anti-icing experiments show that the composite has good corrosion resistance, infrared stealth, and thermal insulation properties. Therefore, this work provides an effective strategy for obtaining thin-thickness, light-weight, and high-performance EMW absorption materials, embodying the advantages of N-RGO/CoSe2 composites in practical applications.
引用
收藏
页数:14
相关论文