Electroreductive Ring-Opening Carboxylation of 1,3-Oxazolidin-2-ones with CO2 for Accessing β-Amino Acids

被引：3

作者：

Tao, Li ^{[1
]}

Liu, Xiao-Fei ^{[1
]}

Ren, Bai-Hao ^{[1
]}

Wang, He ^{[1
]}

Sun, Hui-Qin ^{[1
]}

Zhang, Ke ^{[1
]}

Teng, Yong-Qiang ^{[1
]}

Ren, Wei-Min ^{[1
]}

Lu, Xiao-Bing ^{[1
]}

Zhang, Wen-Zhen ^{[1
]}

机构：

[1] Dalian Univ Technol, Frontiers Sci Ctr Smart Mat, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 02期

基金：

中国国家自然科学基金;

关键词：

ELECTROCARBOXYLATION;

D O I：

10.1021/acs.orglett.3c04007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrocarboxylation of the C(sp(3))-O bond in 1,3-oxazolidin-2-ones with CO2 to achieve beta-amino acids is developed. The C-O bond in substrates can be selectively cleaved via the single electron transfer on the surface of a cathode or through a CO2 center dot (-) intermediate under additive-free conditions. A great diversity of beta-amino acids can be obtained in a moderate to excellent yield and readily converted to various biologically active compounds.

引用

页码：542 / 546

页数：5

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