Phenanthro[9,10-d ]imidazoles: An Unexpected Synthetic Route

被引：0

作者：

Springer, Bastian L. ^{[1
]}

Holzschneider, Kristina ^{[1
]}

Mohr, Fabian ^{[2
]}

Kirsch, Stefan F. ^{[1
]}

机构：

[1] Berg Univ Wuppertal, Organ Chem, Gaussstr 20, D-42119 Wuppertal, Germany

[2] Berg Univ Wuppertal, Inorgan Chem, Gaussstr 20, D-42119 Wuppertal, Germany

来源：

SYNTHESIS-STUTTGART | 2023年 / 55卷 / 24期

关键词：

azides; fragmentations; amines; heterocycles; amides; IMIDAZOLE; CHEMISTRY;

D O I：

10.1055/s-0042-1751493

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthetic route for the synthesis of phenanthro[9,10-d]imidazoles is described. Through aminolysis of easily accessible 10,10-diazidophenanthren-9(10H)-one with nucleophilic amines, a self-condensation is triggered that results in the formation of the target phenanthro[9,10-d]imidazoles. The molecular structures were studied by X-ray single crystallography, and the optical properties of the material are described.

引用

页码：4224 / 4230

页数：7

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