Hydrogenation of furfural to tetrahydrofurfuryl alcohol over nickel-supported on organoclay catalyst

被引：6
|
作者：
Kamble, Paresh A. [1 ]
Vinod, C. P. [2 ,3 ]
Rathod, Virendra K. [1 ]
Kantam, Mannepalli Lakshmi [1 ]
机构：
[1] Inst Chem Technol, Dept Chem Engn, Mumbai 400019, India
[2] CSIR Natl Chem Lab, Catalysis & Inorgan Chem Div, Dr Homi Bhabha Rd, Pune 411008, India
[3] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India
来源：
APPLIED CATALYSIS A-GENERAL | 2024年 / 674卷
关键词：
Nickel; Organoclay; Hydrogenation; Furfural; Tetrahydrofurfuryl alcohol; SOLUTION COMBUSTION METHOD; SELECTIVE HYDROGENATION; XPS SPECTRA; THIN-FILMS; CONVERSION; CYCLOPENTANOL; BIOMASS; SURFACE; ACID; COMPOSITE;
D O I：
10.1016/j.apcata.2024.119621
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Nickel supported on organoclay prepared by the impregnation method provides excellent catalytic activity for the hydrogenation of furfural to tetrahydrofurfuryl alcohol. The relative amount of metal and acidic sites influences the hydrogenation reaction. Additionally, by varying the temperature and the H-2 pressure, we can regulate the interaction of furfural with the active sites. And this may decide the fate of the reaction whether it will undergo a two-step hydrogenation to form tetrahydrofurfuryl alcohol or a rearrangement reaction to form cyclopentanone/cyclopentanol. Water was found to be the best solvent for the selective formation of tetrahydrofurfuryl alcohol. Even though alcohols inhibited rearrangement reaction, the hydrogenation of furfural was more selective towards furfuryl alcohol. Ni/O-clay30A under the optimum conditions of 120 degrees C, 4.0 MPa, and in 1 h offered complete conversion of furfural to tetrahydrofurfuryl alcohol.
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页数：14
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