Effect of Chemical and Steam Explosion Pulping on the Physical and Mechanical Properties of Sugarcane Straw Pulp Trays

被引:0
|
作者
Ngiwngam, Kittaporn [1 ,2 ]
Chinvorarat, Sinchai [3 ]
Rachtanapun, Pornchai [4 ,5 ,6 ]
Auras, Rafael [7 ]
Wittaya, Thawien [8 ]
Tongdeesoontorn, Wirongrong [1 ,2 ]
机构
[1] Mae Fah Luang Univ, Sch Agroind, 333 Moo 1 Tasud, Chiang Rai 57100, Thailand
[2] Mae Fah Luang Univ, Res Grp Innovat Food Packaging & Biomat Unit, 333 Moo 1 Tasud, Chiang Rai 57100, Thailand
[3] King Mongkuts Univ Technol North Bangkok, Dept Mech & Aerosp Engn, Bangkok 10800, Thailand
[4] Chiang Mai Univ, Fac Agroind, Sch Agroind, Div Packaging Technol, Chiang Mai 50100, Thailand
[5] Chiang Mai Univ, Ctr Excellence Agro Biocircular Green Ind Agro BCG, Chiang Mai 50100, Thailand
[6] Chiang Mai Univ, Ctr Excellence Mat Sci & Technol, Chiang Mai 50200, Thailand
[7] Michigan State Univ, Sch Packaging, 448 Wilson Rd, E Lansing, MI 48824 USA
[8] Prince Songkla Univ, Fac Agroind, Hat Yai 90110, Thailand
关键词
sugarcane straw fiber; chemical pulping; steam explosion; hydraulic molding; mechanical properties; CANE STRAW; CELLULOSE; FIBER; LIGNIN; FRACTIONATION; IMPREGNATION; PRETREATMENT; DEGRADATION; EXTRACTION; NAOH;
D O I
10.3390/polym15143132
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Sugarcane straw fiber (SSF) samples were prepared by chemical pulping (CP) and steam explosion (STE). CP (5, 10, 15% NaOH + 0.2% w/w anthraquinone at 121 & DEG;C for 1 h) and STE pressure (1.77, 1.96, and 2.16 MPa at 220 & DEG;C for 4 min) SSF trays were molded with a hydraulic hot-press machine at 120 & DEG;C, 7 min, and 1.72 MPa. The yield (%) of SSF from STE (54-60% dry basis (db.)) was higher than CP (32-48% db.). STE trays had greater tensile strength than CP. However, STE's elongation and compression strength was lower than CP tray samples. The trays made from SSF using STE had less swelling in thickness, longer water wetting time, and a higher water contact angle than those made from CP. The micrographs displayed a smaller size of SSF obtained in STE than the CP. The appearance and area of peaks in ATR-FTIR spectra and XRD diffractograms, respectively, revealed that the STE trays had a larger residual lignin content from the lignin study and a lower crystallinity index than the CP trays. Moreover, the lightness values of the STE trays were lower than those of the CP trays due to lignin retention. The study results indicate that CP is the preferred method for producing SSF packaging material with high flexibility and fiber purity. However, when considering the specific SF of 4.28, the STE treatment showed superior physical and mechanical properties compared to CP. This suggests that STE could be an excellent alternative green pulping technique for producing durable biobased trays. Overall, the findings highlight the potential of STE as a viable option for obtaining trays with desirable characteristics, providing a sustainable and efficient approach to tray production.
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页数:18
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