Ignition limits of hydrogen-methane-air mixtures over metallic Rh at a pressure of 1-2 atm

被引：1

作者：

Rubtsov, Nikolai M. ^{[1
]}

Chernysh, Victor I. ^{[1
]}

Tsvetkov, Georgii I. ^{[1
]}

Troshin, Kirill Ya. ^{[2
]}

Shamshin, Igor O. ^{[2
]}

机构：

[1] Russian Acad Sci, Inst Struct Macrokinet & Mat Sci, Moscow 142432, Russia

[2] Russian Acad Sci, NN Semenov Fed Res Ctr Chem Phys, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 04期

关键词：

ignition; flame; combustion; hydrogen-methane mixture; rhodium; high-speed color filming; NATURAL-GAS; COMBUSTION; SURFACE;

D O I：

10.1016/j.mencom.2023.06.043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ignition temperatures and effective activation energies of the ignition limits of mixtures (40-70% H2 + 60-30% CH4)stoich + air over Rh were experimentally determined at a pressure of 1 atm in the temperature range 20-300 & DEG;C. Over an ignition-treated Rh surface, the ignition temperature of a mixture of 70% H2 + 30% methane + air is 62 & DEG;C. This indicates the potential of using Rh to markedly lower the ignition temperature of fuels based on hydrogen-methane mixtures.

引用

页码：574 / 576

页数：3

共 21 条

[1] Ignition Limits of Hydrogen-Methane-Air Mixtures Over Metallic Rhodium at a Pressure of up to 2 atm
Troshin, K. Ya.
Rubtsov, N. M.
Tsvetkov, G. I.
Chernysh, V. I.
Shamshin, I. O.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2023, 17 (02) : 433 - 438
[2] Ignition Limits of Hydrogen–Methane–Air Mixtures Over Metallic Rhodium at a Pressure of up to 2 atm
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V. I. Chernysh
I. O. Shamshin
Russian Journal of Physical Chemistry B, 2023, 17 : 433 - 438
[3] Ignition of hydrogen-methane-air mixtures over Pd foil at atmospheric pressure
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[4] Initiation of Hydrogen-Air Mixtures with Metallic Rh and Hydrogen-Methane/Ethane/Ethylene-Air Mixtures with Pd and Rh at Pressures of 1-2 atm
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[5] Initiation of Hydrogen–Air Mixtures with Metallic Rh and Hydrogen–Methane/Ethane/Ethylene–Air Mixtures with Pd and Rh at Pressures of 1–2 atm
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[6] Catalytic Ignition of Deuterium-Air Mixtures Over a Metallic Rhodium Surface at Pressures of 1-2 ATM
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[7] Ignition of Hydrogen-Hydrocarbon (C1-C6)-Air Mixtures over the Palladium Surface at 1-2 Atm
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