A New Modified Method to Obtain a High Melt Index of PLA Polymer and Preparation of Melt-Blown Nonwoven Cloth

被引:3
|
作者
Lin, Qian [1 ]
Feng, Jianyong [1 ,2 ,3 ]
Zhao, Lixia [4 ]
机构
[1] Zhejiang Sci Tech Univ, Int Inst Silk, Coll Text Sci & Engn, 928, 2nd St, Xiasha Higher Educ Zone, Hangzhou 310018, Peoples R China
[2] Key Lab Intelligent Text & Flexible Interconnect Z, Hangzhou, Peoples R China
[3] Univ Cambridge, Cavendish Lab, J J Thomson Ave, Cambridge CB3 0HE, England
[4] Chongqing Relayde Med Technol Co Ltd, Bldg C-1, 5 Quanbei 1st Rd, Yanjiahe, Chongqing 401220, Peoples R China
关键词
High melting index; PLA; Melt-blown nonwoven; Sub-micron fibers; Degradable; DEGRADATION; BEHAVIOR; CRYSTALLIZATION; BIODEGRADATION; TEMPERATURE; PERFORMANCE; NANOFIBER; BLENDS; FIBER; ACID;
D O I
10.1007/s12221-023-00317-2
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
Due to the low melt index of polylactic acid (PLA) polymer, it is difficult to melt-blown processing. Here, a new modified method to obtain a high melt index of PLA polymer and melt-blown nonwoven cloth was studied. PLA polymers are modified by the thermally degraded method of stannous octoate (Sn(Oct)2) and polyethylene glycol (PEG) to obtain a high melt index (1054 g/10 min) in comparison with a low melt index (23 g/10 min) of original unmodified PLA polymer. The fiber of modified PLA polymer melt-blown cloth is obviously thinner, having sub-micron fibers, the smallest fiber is about 200 nm. From our test, modified PLA polymer melt-blown cloth has good oil absorption, oil-water separation, and potential air filtration property. In terms of degradation, the modified PLA polymer melt-blown cloth showed excellent degradation performance in basic aqueous solutions at 55 & DEG;C at pH 12, reaching a degradation rate of around 95% at 60 h.
引用
收藏
页码:3405 / 3419
页数:15
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