Groundnut shell chemically treated with KOH to prepare inexpensive activated carbon: Methylene blue adsorption and equilibrium isotherm studies

被引:34
|
作者
Mani, Durai [1 ]
Elango, Duraisamy [2 ]
Al-Humaid, Latifah A. [4 ]
Ragupathy, S. [5 ,6 ]
Jayanthi, Palaniyappan [2 ]
Ahn, Young -Ho [1 ]
Priyadharsan, A. [3 ]
Al-Dahmash, Nora Dahmash [4 ]
机构
[1] Yeungnam Univ, Dept Civil Engn, Environm Sci & Engn Lab, Gyongsan 38541, South Korea
[2] Periyar Univ, Dept Environm Sci, Salem 636011, Tamil Nadu, India
[3] Saveetha Inst Med & Tech Sci SIMATS, Saveetha Dent Coll & Hosp, Dept Conservat Dent & Endodont, Chennai 600077, Tamil Nadu, India
[4] King Saud Univ, Coll Sci, Dept Bot & Microbiol, Riyadh 11451, Saudi Arabia
[5] ERK Arts & Sci Coll, Dept Phys, Dharmapuri 636905, Tamil Nadu, India
[6] Govt Arts & Sci Coll Women, Dept Phys, Dharmapuri 635111, Tamil Nadu, India
基金
新加坡国家研究基金会;
关键词
Adsorption; Groundnut shell activated carbon; Isotherms; Methylene blue dye; BIOMASS;
D O I
10.1016/j.envres.2023.116026
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Groundnut shell activated carbon (GNSAC) is made from groundnut shells using potassium hydroxide (KOH) at 600 degrees C in a nitrogen atmosphere. The properties of the products were examined using FT-IR, XRD, SEM with EDS, and BET analysis. The activating temperature of 600 degrees C and the impregnation ratio of 1:1 were observed as optimum for achieving the highest surface area (412 m2/g). The adsorption efficiency of optimized GNSAC (1:1) was evaluated using a methylene blue (MB) dye solution. The effects of contact time, pH, adsorbent dose, and beginning dye concentration on the removal efficiency of MB were investigated among the GNS/KOH ratios of a 1:1 sample used as the adsorbent. Additionally, the Langmuir and Freundlich adsorption models were used to support the adsorption isotherms. According to the adsorption data at these ideal conditions, GNSAC is capable of absorbing 83.33 mg/g of dye at equilibrium as demonstrated by the Langmuir isotherm. This result demon-strates that GNSAC is a potentially useful material for wastewater treatment.
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页数:7
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