Contaminant characterization of odor in soil of typical pesticide-contaminated site with shallow groundwater

Odor emission from the soil of pesticide-contaminated sites is a prominent environmental problem in China, but there are very few researches about the component and spatial distribution of odorous substances in the soil of contaminated sites. In this paper, to investigate the odor pollution condition of an organophosphorus pesticide production site in a city of South China, the odor pollutants in the soil and soil gas were analyzed and the key odor-contributing substances were identified. Besides, the correlation between the concentrations of odorous substances in soil and soil gas was analyzed, and the measured results were compared with the predicted results by the linear model and DED model. An off-line soil gas sampling device was designed to collect the gas emitted from soil because the groundwater level in the site was too shallow to build a soil gas well. The key odor substances were screened from the detection results of soil gas via odor activity value (OAV) analysis, which revealed that the key odorous substances included benzene, ethylbenzene, ammonia, toluene, m,p-xylene, methyl sulfide, dimethyl disulfide, and formaldehyde. Furthermore, the spatial distribution of the odor substances in the soil of the pesticide-contaminated site was closely related to the layout and geologic structure of the site. The odor pollutants in soil were mainly distributed near the phosmet production workshop and the drainage ditch network. As for the deep distribution, the odorous substances were mainly enriched in the silty clay or clay layer (5.6-11 m), followed by the sludge layer (1-3.6 m). Finally, the predicted model (linear model and DED model) analysis suggested that the linear model was more suitable for predicting the concentration of odorous substances in the soil gas with the detection data of soil in this pesticide-contaminated site.