Total synthesis of (3R, 4S)-4-hydroxylasiodiplodin

被引：0

作者：

Sheelam, Kalidasu ^{[1
,2
]}

Chidara, Sridhar ^{[2
]}

Vinnakota, Srilalitha ^{[3
]}

Sridhar, Gattu ^{[4
]}

Polothi, Ravikumar ^{[1
,2
]}

机构：

[1] JNT Univ, Dept Chem, Hyderabad, Telangana, India

[2] GVK Biosci Private Ltd, Hyderabad, Telangana, India

[3] ICFAI Fdn Higher Educ, Fac Sci & Technol, Dept Chem, Hyderabad, Telangana, India

[4] Kakatiya Inst Technol & Sci, Dept Chem, Warangal, Andhra Pradesh, India

来源：

NATURAL PRODUCT RESEARCH | 2023年 / 37卷 / 08期

关键词：

Resorcylic acid lactones; (3R; 4S)-4-hydroxylasiodiplodin; Stille cross coupling; hydroboration; Yamaguchi macrolactonization; RESORCYLIC ACID LACTONES; METABOLITES; LASIODIPLODINS; MACRODIOLIDE; ZEARALENONE; KINASE;

D O I：

10.1080/14786419.2021.2003354

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient stereoselective total synthesis of (3R, 4S)-4-hydroxylasiodiplodin has been accomplished starting from known starting materials. The key steps involved in this synthesis are Stille cross coupling, alkylation of 1,3-dithiane and Yamaguchi macrolactonization.

引用

页码：1277 / 1283

页数：7

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