A new compound Na5Mn4(PO4)4F4.2H2O with a rarely mixed valence spin chain showing multiple magnetic transitions

被引：1
|
作者：
Luo, Qi [1 ,2 ]
Li, Ningxia [1 ]
Zhao, Zhiying [1 ]
Cui, Meiyan [1 ]
He, Zhangzhen [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
来源：
INORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 21期
基金：
中国国家自然科学基金;
关键词：
HALDANE-GAP; ANTIFERROMAGNET; BEHAVIOR; RANGE;
D O I：
10.1039/d3qi01389h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound Na5Mn4(PO4)(4)F-4 center dot 2H(2)O was successfully obtained, featuring a typical channel structure composed of rarely mixed valence Mn2+/Mn3+ spin chains and PO4 tetrahedra, where H2O molecules are located inside the channels. Magnetic measurements show that this compound possesses successive multiple magnetic transitions at low temperature.
引用
收藏
页码：6303 / 6307
页数：5
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