Oxidative and Nonoxidative Conversion of Ethylene in Dielectric Barrier Discharge

被引：0
|
作者：
Ryabov, A. Yu. [1 ]
Kudryashov, S. V. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Inst Petr Chem, Tomsk 634055, Russia
来源：
HIGH ENERGY CHEMISTRY | 2023年 / 57卷 / 04期
关键词：
ethylene; dielectric barrier discharge; oxidation; nonoxidative conversion; kinetics; PROPYLENE OXIDATION; KINETIC DATA; CHEMISTRY; MECHANISM; FEATURES; METHANE; WATER;
D O I：
10.1134/S0018143923040124
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The oxidative and nonoxidative conversion of ethylene in a dielectric barrier discharge in the presence of water with the formation of predominantly unsaturated compounds (acetylene, butene, butadiene) has been studied. The efficiency of ethylene conversion in argon is shown in comparison with its oxidation by air into oxygenates. A simple theoretical estimate of the energy loss of discharge electrons in the feed gas mixture and simple kinetic calculations make it possible to explain both the change in the degree of ethylene conversion and the direction of the process.
引用
收藏
页码：364 / 368
页数：5
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