Stepwise assembly of heterometallic, heteroleptic "triblock Janus-type" metal-organic polyhedra

被引：3

作者：

von Baeckmann, Cornelia ^{[1
,2
,3
]}

Ruiz-Relano, Sara ^{[1
,2
,3
]}

Imaz, Inhar ^{[1
,2
,3
]}

Handke, Marcel ^{[1
,2
,3
]}

Juanhuix, Judith ^{[4
]}

Gandara, Felipe ^{[5
]}

Carne-Sanchez, Arnau ^{[1
,2
,3
]}

Maspoch, Daniel ^{[1
,2
,3
,6
]}

机构：

[1] CSIC, Catalan Inst Nanosci & Nanotechnol ICN2, Campus UAB, Bellaterra 08193, Barcelona, Spain

[2] Barcelona Inst Sci & Technol, Campus UAB, Bellaterra 08193, Barcelona, Spain

[3] Univ Autonoma Barcelona, Dept Quim, Bellaterra 08193, Spain

[4] Alba Synchrotron Light Facil, Cerdanyola Valles, Barcelona 08290, Spain

[5] CSIC, Mat Sci Inst Madrid ICMM, Calle Sor Juana Ines Cruz 3, Madrid 28049, Spain

[6] ICREA, Pg Lluis Companys 23, Barcelona 08010, Spain

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 23期

关键词：

RETICULAR CHEMISTRY; MULTICOMPONENT; CAGES;

D O I：

10.1039/d2cc06815j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Increasing the chemical complexity of metal-organic cages (MOCs) or polyhedra (MOPs) demands control over the simultaneous organization of diverse organic linkers and metal ions into discrete caged structures. Herein, we show that a pre-assembled complex of the archetypical cuboctahedral MOP can be used as a template to replicate such caged structure, one having a "triblock Janus-type" configuration that is both heterometallic and heteroleptic.

引用

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页码：3423 / 3426

页数：4

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