Photocatalyst-free visible-light-mediated three-component reaction of α-diazoesters, cyclic ethers and NaSCN to access organic thiocyanates

被引：69
|
作者：
Wang, Zhiwei [1 ]
Meng, Na [1 ]
Lv, Yufen [1 ]
Wei, Wei [1 ,2 ,3 ]
Yue, Huilan [2 ,3 ]
Zhong, Guofu [1 ]
机构：
[1] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Peoples R China
[2] Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Peoples R China
[3] Northwest Inst Plateau Biol, CAS Key Lab Tibetan Med Res, Xining 810008, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2023年 / 34卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Photocatalyst-free; Visible-light; Three-component reaction; Organic thiocyanates; INDUCED DEOXYGENATIVE C2-SULFONYLATION; QUINOLINE N-OXIDES; ALKYL THIOCYANATES; CATALYST; REAGENT; THIOLS; ROUTE; MILD;
D O I：
10.1016/j.cclet.2022.06.022
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A facile and environmentally friendly visible-light-induced three-component reaction of alpha-diazoesters, cyclic ethers and NaSCN to construct organic thiocyanates has been developed at room temperature. This reaction could occur under photocatalyst-and additive-free conditions to afford a number of organic thiocyanates with moderate to good yield and favorable functional group tolerance. (c) 2022 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
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页数：4
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