Phase equilibria, structural and thermodynamic properties of phases in the nickel (II) methanesulfonate - Water, cobalt (II) methanesulfonate - Water and manganese (II) methanesulfonate - Water systems

被引：3
|
作者：
Belova, Ekaterina, V [1 ]
Shakirova, Julia D. [1 ]
Lyssenko, Konstantin A. [1 ,2 ]
Mikheev, Ivan, V [1 ]
Maliutin, Alexey S. [1 ]
Kovalenko, Nikita A. [1 ]
Uspenskaya, Irina A. [1 ]
机构：
[1] Lomonosov MSU, Chem Dept, Moscow 119991, Russia
[2] GV Plekhanov Russian Univ Econ, 36 Stremyanny Per, Moscow 117997, Russia
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2023年 / 182卷
基金：
俄罗斯科学基金会;
关键词：
Cobalt methanesulfonate; Nickel methanesulfonate; Manganese methanesulfonate; Pitzer-Simonson-Clegg model; Phase equilibria; Static method; Water activity; Crystal structures of methanesulfonates; ION BATTERY; RECOVERY; METALS; ACID; MAGNESIUM; CO; LI;
D O I：
10.1016/j.jct.2023.107049
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Solid-liquid equilibria in the Ni(CH3SO3)(2)-H2O, Co(CH3SO3)(2)-H2O, and Mn(CH3SO3)(2)-H2O systems were studied by isothermal solubility and DSC methods. TG and X-Ray diffraction were used to identify solid phases in equilibria with the solution. Water vapor pressure was determined by static method at 288.15 K, 298.15, and 308.15 K in the Ni(CH3SO3)(2)-H2O, Co(CH3SO3)(2)-H2O and Mn(CH3SO3)(2)-H2O systems. Based on vapor-liquid (VLE) and solid-liquid (SLE) equilibria data, parameters of the Pitzer-Simonson-Clegg model were obtained. Stability parameters of the hydrates Ni(CH3SO3)(2)center dot 12H(2)O, Ni(CH3SO3)(2)center dot 6H(2)O, Co(CH3SO3)(2)center dot 4H(2)O, Co (CH3SO3)(2)center dot 9H(2)O, Co(CH3SO3)(2)center dot 6H(2)O, Mn(CH3SO3)(2)center dot 12H(2)O, and Mn(CH3SO3)(2)center dot 2H(2)O were estimated. Binary phase diagram fragments were calculated.
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页数：12
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