Mechanochemical degradation performance of lindane in different types of soils: The effects of soil properties and elemental components

Although mechanochemical remediation of organic-contaminated soil has received substantial attention in recent years, the effects of soil properties on soil remediation performance are not clear. In this work, the properties and elemental components of 16 soils were tested, and the mechanochemical degradation performance of lindane in these soils was investigated through experiments. Most importantly, the relationships between soil variables and the mechanochemical degradation rates of lindane in the additive-free and CaO systems were elucidated. The results showed that the mechanochemical degradation efficiencies of lindane in the 16 soils were significantly different without additives, with a range of 31.0 %-97.2 % after 4 h. The mechanochemical degradation rates of lindane in the 16 soils varied from 0.7 h(-1) to 15 h(-1) after the addition of 9 % CaO. Correlation analysis, redundancy analysis and the partial least squares path modeling results clearly showed that the main factors affecting the reaction rate (k(1)) without additives were organic matter (-) > clay (+) > bound water (-) > Si (+). After the addition of 9 % CaO, the order in which the main factors affected the reaction rate (k(2)) was organic matter (-) > bound water (-) > Ti/Fe/Al (-) > pH (+) > clay (+). The established and corrected multiple nonlinear regression equations can be used to accurately predict the mechanochemical degradation performance of hexachlorocyclohexanes in actual soils with and without additives.