Heat, pH, and salt: synthesis strategies to favor formation of near-infrared emissive DNA-stabilized silver nanoclusters

被引:7
|
作者
Guha, Rweetuparna [1 ]
Rafik, Malak [1 ]
Gonzalez-Rosell, Anna [1 ]
Copp, Stacy M. [1 ,2 ,3 ]
机构
[1] Univ Calif Irvine, Dept Mat Sci & Engn, Irvine, CA 92697 USA
[2] Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA
[3] Univ Calif Irvine, Dept Chem & Biomol Engn, Irvine, CA 92697 USA
关键词
MEDIATED BASE-PAIRS; FLUORESCENCE; SEQUENCE;
D O I
10.1039/d3cc02896h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present chemical synthesis strategies for DNA-stabilized silver nanoclusters (Ag-N-DNAs) with near-infrared (NIR) emission in the biological tissue transparency windows. Elevated temperatures can significantly increase chemical yield of near-infrared nanoclusters. In most cases, basic pH favors near-infrared nanoclusters while micromolar amounts of NaCl inhibit their formation.
引用
收藏
页码:10488 / 10491
页数:5
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