Influence of the Mechanochemical Modification of Humic Acids on the Formation of Colloids in Solution

被引:0
|
作者
Yudina, N. V. [1 ]
Savel'eva, A. V. [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, Inst Petr Chem, Tomsk 634055, Russia
关键词
brown coal; mechanical activation; humic acids; colloidal properties; BROWN-COAL; SUBSTANCES; ASSOCIATION; PH;
D O I
10.3103/S0361521923050075
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The colloid-chemical properties of humic acids (HAs) were studied depending on the mechanochemical modification of their structure. An increase in the amount of acidic ionogenic groups and hydrophilic fragments in the composition of modified HAs facilitated a decrease in the excess energy of surface molecules. In an alkaline solution, two types of colloids characterized by a decrease in the energy of adsorption and the constant of adsorption equilibrium were formed as the concentration of HAs was increased.
引用
收藏
页码:314 / 318
页数:5
相关论文
共 50 条
  • [1] Influence of the Mechanochemical Modification of Humic Acids on the Formation of Colloids in Solution
    N. V. Yudina
    A. V. Savel’eva
    Solid Fuel Chemistry, 2023, 57 : 314 - 318
  • [2] Mechanochemical modification of peat humic acids
    A. V. Savel’eva
    N. V. Yudina
    Solid Fuel Chemistry, 2014, 48 : 328 - 331
  • [3] Mechanochemical modification of peat humic acids
    Savel'eva, A. V.
    Yudina, N. V.
    SOLID FUEL CHEMISTRY, 2014, 48 (05) : 328 - 331
  • [4] The influence of mechanochemical modification on prevention of toxic ability of humic acids towards phenanthrene in aquatic environment
    Shekhovtsova, N. S.
    Maltseva, E. V.
    Glyzina, T. S.
    Ovchinnikova, I. S.
    XIX INTERNATIONAL SCIENTIFIC SYMPOSIUM IN HONOR OF ACADEMICIAN M.A. USOV PROBLEMS OF GEOLOGY AND SUBSURFACE DEVELOPMENT, 2015, 27
  • [5] Effect of mechanochemical modification on the surfactant and structural properties of humic and himatomelanic acids
    Mal'tseva, E. V.
    Shekhovtsova, N. S.
    Shilyaeva, L. P.
    Yudina, N. V.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (07) : 1273 - 1278
  • [6] Effect of mechanochemical modification on the surfactant and structural properties of humic and himatomelanic acids
    E. V. Mal’tseva
    N. S. Shekhovtsova
    L. P. Shilyaeva
    N. V. Yudina
    Russian Journal of Physical Chemistry A, 2017, 91 : 1273 - 1278
  • [7] Specific Features of the Formation of Adsorption Layers from Products of Mechanochemical Modification of Humic Acids at a Liquid–Gas Interface
    S. L. Khil’ko
    M. I. Rogatko
    R. A. Makarova
    R. G. Semenova
    Colloid Journal, 2020, 82 : 746 - 757
  • [8] Specific Features of the Formation of Adsorption Layers from Products of Mechanochemical Modification of Humic Acids at a Liquid-Gas Interface
    Khil'ko, S. L.
    Rogatko, M. I.
    Makarova, R. A.
    Semenova, R. G.
    COLLOID JOURNAL, 2020, 82 (06) : 746 - 757
  • [9] Mechanochemical modification of the structure of brown coal humic acids for preparing a sorbent for heavy metals
    Urazova, T. S.
    Bychkov, A. L.
    Lomovskii, O. I.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2014, 87 (05) : 651 - 655
  • [10] Mechanochemical modification of the structure of brown coal humic acids for preparing a sorbent for heavy metals
    T. S. Urazova
    A. L. Bychkov
    O. I. Lomovskii
    Russian Journal of Applied Chemistry, 2014, 87 : 651 - 655