Sorption Capacity of Polydimethylsiloxane Foams Filled with Thermal-Treated Bentonite-Polydimethylsiloxane Composite Foams for Oil Spill Remediation

被引:1
|
作者
Calabrese, Luigi [1 ]
Piperopoulos, Elpida [1 ]
Jovanovic, Vesna Stankov [2 ]
Nikolic, Jelena [2 ]
Ciric, Slobodan [2 ]
Milone, Candida [1 ]
Proverbio, Edoardo [1 ]
机构
[1] Univ Messina, Dipartimento Ingn, Dio St Agata, I-98166 Messina, Italy
[2] Univ Nis, Fac Sci & Math, Dept Chem, Visegradska 33, Nish 18000, Serbia
关键词
oil recovery; foam; siloxane; bentonite; sorption kinetics; oil-water selectivity; PHYSICOCHEMICAL PROPERTIES; ADSORPTION; BIOREMEDIATION; ABSORPTION;
D O I
10.3390/ma16134818
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The spillage of oil causes severe and long-lasting impacts on both the environment and human life. It is crucial to carefully reconsider the methods and techniques currently employed to recover spilled oil in order to prevent any possible secondary pollution and save time. Therefore, the techniques used to recover spilled oil should be readily available, highly responsive, cost-effective, environmentally safe, and, last but not least, they should have a high sorption capacity. The use of sorbents obtained from natural materials is considered a suitable approach for dealing with oil spills because of their exceptional physical characteristics that support sustainable environmental protection strategies. This article presents a novel sorbent material, which is a composite siloxane foam filled with bentonite clay, aimed at enhancing the hydrophobic and oleophilic behavior of the material. The thermal treatment of bentonite optimizes its sorption capacity by eliminating water, and increasing the surface area, and, consequently, its interaction with oils. In particular, the maximum sorption capacity is observed in kerosene and naphtha for the bentonite clay thermally treated at 600 & DEG;C, showing an uptake at saturation of 496.8% and 520.1%, respectively. Additionally, the reusability of the composite foam is evaluated by squeezing it after reaching its saturation point to determine its sorption capacity and reusability.
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页数:15
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