Embedding antimony nanoparticles into metal-organic framework derived TiO2 @carbon nanotablets for high-performance sodium storage

Titanium dioxide (TiO 2 ) has been widely investigated as a candidate for anode materials of sodium-ion batteries (SIBs) due to its low cost and high abundance. However, the intrinsic sluggish ion/electron transfer rate hinders its practical applications for high energy density storage devices. In contrast, antimony (Sb) shows high specific theoretical capacity (660 mAh/g) as well as excellent electron conductivity, but the large volume variation upon cycling usually leads to severe capacity fading. Herein, with the objective of achieving high-performance sodium storage anode materials, TiO 2 @C-Sb nanotablets with a small amount of Sb content (6.4 wt%) are developed through calcination Ti-metal-organic framework (MIL-125) derived TiO 2 @C/SbCl 3 mixture under reductive atmosphere. Benefitting from the synergetic effect of welldispersed Sb nanoparticles as well as robust porous TiO 2 @C substrate, the TiO 2 @C-Sb shows enhanced electron/ion transfer rate and predominantly pseudocapacitive sodium storage behavior, delivering a reversible capacity of 219 mAh/g at 0.5 A/g even after 10 0 0 cycles. More significantly, this method may be commonly used to incorporate other alloy-based high-theoretical materials into MIL-125-derived TiO 2 @C, which is promising for developing high-energy-density TiO 2 -based energy storage devices. & COPY; 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.