Currently, the development of CsSnI3 perovskite is still greatly hindered by their intrinsic deficiencies, such as their easy phase transformation. To address this issue, we theoretically constructed Dion-Jacobson (DJ) perov-skites intercalated by divalent 1,5-pentamethylenediamine (PeDA2+) exhibit significantly enhanced phase sta-bility. However, the carrier mobility is always depressed owing to the charge localization and severe lattice distortion in the presence of spacers among wafers. Thus, the alkyl ligand cations (e.g., ethylenediamine (EDA), 1,3-propanediamine (PDA), 1,4-butanediamine (BDA)) with varying lengths as organic intercalators are exam-ined for optimizing charge transfer. Compared with the other configures, the (PDA)Cs2Sn3I10 exhibits the most significantly improved stability due to the enhanced chemical bonding and faintest structural distortions, as evidenced by computed the formation enthalpy. Formation energy and transition level of tin-vacancy defect further confirm the improved stability and depressed defect-trapping states. Meanwhile, 2D-(PDA)Cs2Sn3I10 exhibit obviously increased electrical conductivity and reduced carrier effective masses, which might benefit the photoelectric conversion of solar cells.
