TmVO4/Fe2O3 nanocomposites: Sonochemical synthesis, characterization, and investigation of photocatalytic activity

被引:35
|
作者
Panahi, Atefeh [1 ]
Monsef, Rozita [1 ]
Imran, Merzah Kareem [2 ]
Mahdi, Ayat Abdul [3 ]
Ruhaima, Ali Abdul Kadhim [4 ]
Salavati-Niasari, Masoud [1 ]
机构
[1] Univ Kashan, Inst Nano Sci & Nano Technol, POB 87317-51167, Kashan, Iran
[2] AL Mustaqbal Univ Coll, Bldg & Construct Engn Technol Dept, Hillah 51001, Iraq
[3] Al Farahidi Univ, Med Tech Coll, Baghdad, Iraq
[4] AL Nisour Univ Coll, Baghdad, Iraq
基金
美国国家科学基金会;
关键词
TmVO4; Photocatalyst; Water pollution; Sonochemical synthesis; Nanostructures; METHYLENE-BLUE; THERMAL-STABILITY; AQUEOUS-SOLUTION; DEGRADATION; WATER; COMPOSITE; REMOVAL; DYE; NANOPARTICLES; ALPHA-FE2O3;
D O I
10.1016/j.ijhydene.2022.10.226
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Today, a unique method of treating environmental contaminants is drawing considerable attention. Organic dyes are significant wastes from myriad industries, including paper, food, and textiles, which have become a serious environmental concern and have the potential to be toxic to humans and living organisms. This study demonstrates the fabri-cation and characterization of thulium vanadate (TmVO4) nanostructures and TmVO4/ Fe2O3 nanocomposites that were effectively applied in the photodecomposition efficiency of cationic and anionic organic contaminants. The TmVO4/Fe2O3 nanocomposites were prepared through a sonochemical method, and triethylenetetramine (TETA) was employed as a precipitating and capping agent. The tests were performed using a probe as a soni-cation source (60 W, 18 kHz). The impact of TmVO4 content (5, 10, 15, and 30%) on the modification of binary nanocomposites was studied in terms of morphological, optical, and photocatalytic properties. The recyclable magnetic TmVO4/Fe2O3 nanocomposites with 15% TmVO4 achieve 68.3% of eriochrome black t (EBT) utilizing visible origin. More notably, the binary TmVO4/Fe2O3 nanocomposites reveal higher photocatalytic activity than the pure TmVO4 and Fe2O3 nanoparticles.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:3916 / 3930
页数:15
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