External-Cavity Quantum Cascade Laser-Based Gas Sensor for Sulfur Hexafluoride Detection

The external-cavity quantum cascade laser (ECQCL) is an ideal mid-infrared (MIR) spectral light source for determining large molecular-absorption spectral features with broad transition bands. For this paper, a gas sensor system was developed using a broadband tunable ECQCL and a direct absorption spectroscopy detection scheme with a short path absorption cell of 29.6 cm. For spectral signal detection, a cheap and miniaturized quartz crystal tuning fork- (QCTF) based light detector was used for laser signal detection. The characteristics of the QCTF detector were theoretically simulated and experimentally observed. To demonstrate this sensing technique, sulfur hexafluoride (SF6) was selected as the analyte, which can be used as an effective indicator to identify fault-types of gas-insulated electrical equipment. Preliminary results indicated that a good agreement was obtained between experimentally observed data and reference spectra according to the NIST database and previous publications, and the gas sensor system showed a good linear response to SF6 gas concentration. Finally, Allan-Werle deviation analysis indicated that detection limits of 1.89 ppm for SF6 were obtained with a 1 s integration time, which can be further improved to similar to 0.38 ppm by averaging up to 131 s.