Alkylation of furancarboxylic acid derivatives with alkenes catalyzed by nickel complexes with N-heterocyclic carbenes

被引：2
|
作者：
Shepelenko, K. E. [1 ]
Soliev, S. B. [1 ]
Nikolaeva, K. A. [1 ]
Minyaev, M. E. [2 ]
Chernyshev, V. M. [1 ]
机构：
[1] MI Platov South Russian State Polytech Univ NPI, 132 Ul Prosveshcheniya, Novocherkassk 346428, Russia
[2] Russian Acad Sci, N D Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 08期
关键词：
nickel; furans; N-heterocyclic carbenes; CH-alkylation; catalysis; DIRECT ARYLATION; 2,5-FURANDICARBOXYLIC ACID; RECENT PROGRESS; FURANS; FUNCTIONALIZATION; CONVERSION; POLYMERS;
D O I：
10.1007/s11172-023-3956-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient catalytic system based on commercially available nickel source (NiCp2), N-heterocyclic carbene, and a reducing agent (HCOONa) for selective C(5)H-alkylation of amides and esters of 2-furancarboxylic acid with alkenes of various structures was developed. A series of new previously undescribed 5-alkyl derivatives of 2-furancarboxylic acid were synthesized.
引用
收藏
页码：1746 / 1752
页数：7
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