Recent Advances in Nickel Catalyzed Asymmetric Acylation Reactions

被引：8
|
作者：
Zhang Yanyan [1 ]
Zhang Zhuzhu [1 ]
Zhu Shengqing [1 ]
Chu Lingling [1 ]
机构：
[1] Donghua Univ, Coll Chem & Chem Engn, Ctr Adv Low Dimens Mat, Shanghai 201620, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 43卷 / 03期
基金：
中国国家自然科学基金;
关键词：
nickel catalysis; asymmetric acylation; hydroacylation; alkene; STEREOSELECTIVE CONSTRUCTION; COUPLING SYNTHESIS; CARBON-CARBON; PHOTOREDOX; NI; CARBAMOYLATION; ARYLATION; KETONES;
D O I：
10.6023/cjoc202211032
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral.proportional to-carbonyl compounds are important structural units in natural products and pharmaceuticals and versatile synthetic building blocks in organic synthesis. Transition metal-catalyzed asymmetric acylation reaction is one of the most straightforward methods for preparing these compounds. In particular, significant progress has been made in the area of nickel-catalyzed asymmetric acylation reaction, due to the unique properties of nickel catalysts. The latest progress of nickel-catalyzed asymmetric acylation reaction, including nickel-catalyzed asymmetric alkyl-acyl cross-coupling reaction, asymmetric hydroacylation of alkene and asymmetric acyl-functionalization alkene, is summarized.
引用
收藏
页码：1023 / 1035
页数：13
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