Synthesis of Triethylene Glycol-Substituted Phenylterpyridine with a Terminal Aurophilic Group and Its Rh(III) Complex for Adsorption on the Gold Surface

被引：0

作者：

Salimova, I. O. ^{[1
]}

Moiseeva, A. A. ^{[1
]}

Zyk, N. V. ^{[1
]}

Beloglazkina, E. K. ^{[1
]}

机构：

[1] Lomonosov Moscow State Univ, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 59卷 / 05期

关键词：

2,2':6',2"-terpyridines; aurophilic ligands; rhodium(III) complexes; SINGLE; RHODIUM(III); CYTOTOXICITY; SULFOXIDE;

D O I：

10.1134/S1070428023050081

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method for the synthesis of a conjugate of 4-substituted phenylterpyridine and lipoic acid, containing a triethylene glycol linker group between the terpyridine and sulfur-containing fragments, has been developed. A coordination compound of the resulting terpyridine with Rh(III) was obtained. Cyclic voltammetry was used to explore the ability of the synthesized ligand and its rhodium complex to be chemisorbed on the surface of gold electrodes to form an Au-S bond.

引用

页码：793 / 800

页数：8

共 3 条

[1] Synthesis of Triethylene Glycol-Substituted Phenylterpyridine with a Terminal Aurophilic Group and Its Rh(III) Complex for Adsorption on the Gold Surface
I. O. Salimova
A. A. Moiseeva
N. V. Zyk
E. K. Beloglazkina
Russian Journal of Organic Chemistry, 2023, 59 : 793 - 800
[2] Design and synthesis of novel terpyridine-based ligands with one and two terminal aurophilic moieties and their Rh(III) and Ru(II) complexes for the adsorption on metal surfaces
Salimova, Irina O.
Berezina, Anna, V
Shikholina, Ilona A.
Zyk, Nikolai, V
Beloglazkina, Elena K.
POLYHEDRON, 2021, 200
[3] Design and synthesis of novel terpyridine-based ligands with one and two terminal aurophilic moieties and their Rh(III) and Ru(II) complexes for the adsorption on metal surfaces (vol 200, 115149, 2021)
Salimova, Irina O.
V. Berezina, Anna
Moiseeva, Anna A.
Shikholina, Ilona A.
Zyk, Nikolai, V
Beloglazkina, Elena K.
POLYHEDRON, 2021, 210

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