Bimetallic liquid crystal blends based on structurally related 3d-metal coordination complexes

被引：0

作者：

Cretu, Carmen ^{[1
]}

Popa, Evelyn ^{[1
]}

Di Maio, Giuseppe ^{[2
]}

Candreva, Angela ^{[2
]}

Buta, Ildiko ^{[1
]}

Visan, Alexandru ^{[1
]}

La Deda, Massimo ^{[2
]}

Donnio, Bertrand ^{[3
]}

Szerb, Elisabeta I. ^{[1
]}

机构：

[1] Romanian Acad, Coriolan Dragulescu Inst Chem, 24, Mihai Viteazu Bvd, Timisoara 300223, Romania

[2] Univ Calabria, Dept Chem & Chem Technol, I-87036 Arcavacata Di Rende, CS, Italy

[3] Univ Strasbourg, Inst Phys & Chim Materiaux Strasbourg IPCMS, UMR7504, CNRS, F-67034 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 71期

关键词：

ANTICANCER ACTIVITIES; METALLOMESOGENS; 1,10-PHENANTHROLINE;

D O I：

10.1039/d3cc02930a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hetero-bimetallic liquid crystalline materials, exhibiting a single Col(hex) mesophase, were obtained by simple chemical blending between two structurally-related Cu(ii) and Zn(ii) metallomesogens based on 1,10-phenanthroline and two chelating gallate ligands. Mesomorphous and optical properties were modified upon their relative respective proportions. This study highlights the numerous possibilities for the fabrication of new multifunctional polymetallic materials, with the possibility of tuning the properties and controlling supramolecular interactions between metal centres and corresponding synergistic effects.

引用

页码：10616 / 10619

页数：4

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