Photo-controllable Ultralong Room-Temperature Phosphorescence: State of the Art

In this concept, we showcase the upsurge in the studies of dynamic ultralong room-temperature phosphorescence (RTP) materials containing inorganic and/or organic components as versatile photo-responsive platforms. The goal is to provide a comprehensive analysis of photo-controllable RTP, and meanwhile delve into the underlying RTP properties of various classes of photochromic materials including metal-organic complexes, organic-inorganic co-crystals, purely organic small molecules and organic polymers. In particular, the design principles governing the integration of the photochromic and RTP moieties within a single material system, and the tuning of dynamic RTP in response to light are emphasized. As such, this concept sheds light on the challenges and opportunities of using these tunable RTP materials for potential applications in optoelectronics, particularly highlighting their use of reversible information encryption, erasable light printing and rewritable smart paper. The text for Table of Contents: Dynamic persistent luminescence would endow optoelectronic devices with revolutionary performance. In this concept, we have highlighted the recent progress in the photo-switchable room-temperature phosphorescence (RTP) of a series of materials and their potential applications. We also provided a perspective on the future challenges and opportunities for the materials with dynamic phosphorescence.image