Growth Conditions and the Structural and Magnetic Properties of Cu2MBO5 (M = Cr, Fe, Mn) Oxyborates with a Ludwigite Structure

被引:5
|
作者
Moshkina, E. M. [1 ]
Belskaya, N. A. [2 ]
Molokeev, M. S. [1 ,3 ,4 ]
Bovina, A. F. [1 ]
Shabanova, K. A. [5 ,6 ]
Kokh, D. [5 ,6 ]
Seretkin, Yu. V. [7 ,8 ]
Velikanov, D. A. [1 ]
Eremin, E. V. [1 ]
Krylov, A. S. [1 ]
Bezmaternykh, L. N. [1 ]
机构
[1] Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
[2] Russian Acad Sci, Ioffe Inst, St Petersburg 194021, Russia
[3] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[4] Far Eastern State Transport Univ, Khabarovsk 680000, Russia
[5] Reshetnev State Univ Sci & Technol, Krasnoyarsk 660037, Russia
[6] Russian Acad Sci, Fed Res Ctr, Siberian Branch, Krasnoyarsk 660036, Russia
[7] Russian Acad Sci, Sobolev Inst Geol & Mineral, Siberian Branch, Novosibirsk 630090, Russia
[8] Novosibirsk State Univ, Novosibirsk 630090, Russia
基金
俄罗斯科学基金会;
关键词
SINGLE-CRYSTAL;
D O I
10.1134/S1063776123010144
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Copper oxyborate single crystals with a ludwigite structure, Cu2MBO5 (M = Cr, Fe, Mn), containing different substitutes in the trivalent subsystem have been grown from Bi2O3-MoO3-Na2O-B2O3 fluxes. The structural properties of grown compounds have been compared in detail using X-ray diffraction and Raman spectroscopy methods. In addition, these methods have been used to determine the degree of cationic ordering in these ludwigites. The temperature and field dependences of the Cu2MBO5 (M = Cr, Fe, Mn) ludwigite magnetization are presented.
引用
收藏
页码:17 / 25
页数:9
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