Thermodynamic properties of refractory Mo-Nb-V-Ti high entropy alloys (HEAs)

被引:5
|
作者
Beneze, Laszlo [1 ]
Hasemann, Georg [2 ]
Sergeev, Dmitry [3 ]
Motalov, Vladimir [3 ]
Mueller, Michael [3 ]
Krueger, Manja [2 ]
机构
[1] Eotvos Lorand Univ, Inst Chem, Dept Phys Chem, Pazmany Peter Setany 1-A, H-1117 Budapest, Hungary
[2] Otto von Guericke Univ, Inst Mat & Joining Technol G50 5, Univ Pl 2, D-39106 Magdeburg, Germany
[3] Forschungszentrum Julich, Inst Energy & Climate Res IEK 2, D-52425 Julich, Germany
关键词
High entropy alloys; CALPHAD method; Phase diagram; Knudsen effusion mass spectrometry (KEMS); Thermodynamic activity; Regular solution model;
D O I
10.1016/j.jallcom.2023.173279
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High entropy alloys (HEAs) are solid solution alloys containing at least 5 elements in equiatomic or nearequiatomic composition. In the present study we report on an alloy design route for refractory HEAs based on Mo-Nb-V-xTi alloys (x denotes mole per cent of Ti, x = 5, 10, 15, 20, 25, the mole per cents of Mo, Nb, and V are equal). The thermodynamic activities of Ti and V were determined by Knudsen effusion mass spectrometry and the measured data were compared to the calculated data obtained by CALPHAD method.
引用
收藏
页数:12
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