Effects of Al2O3 addition on sintering behaviour, microstructure, and physical properties of Al2O3/vitrified bond CBN composite

The effects of Al2O3 content on the sintering behaviour, microstructure, and physical properties of Al2O3/vitrified bonds (SiO2-Al2O3-B2O3-BaO-Na2O-Li2O-ZnO-MgO) and Al2O3/vitrified bond cubic boron nitride (CBN) composites were systematically investigated using X-ray diffraction, differential scanning calorimetry, dilatometry, scanning electron microscopy, and X-ray photoelectron spectroscopy. Various amounts of Al2O3 promoted the formation of BaAl2Si2O8 and gamma-LiAlSi2O6, increasing the relative crystallinity of the Al2O3/vitrified composite from 85.0 to 93.2%, resulting in residual compressive stress on BaAl2Si2O8, thereby influencing the thermal behaviour and mechanical properties of the Al2O3/vitrified composite. The bulk density, porosity, flexural strength, hardness, and thermal conductivity of 57.5 wt% Al2O3 sintered at 950 degrees C were 3.12 g/cm(3), 6.1%, 169 MPa, 90.5 HRC, and 4.17 W/(m center dot K), respectively. The coefficient of thermal expansion of the bonding material was 3.83 x 10-6 degrees C-1, which was comparable to that of CBN, and the number of N-Al bonds were increased, which boosted the flexural strength of the Al2O3/vitrified CBN composite to 81 MPa. The excellent mechanical properties, compact structure, and suitable interfacial bonding state with the CBN grains of the Al2O3/vitrified composite make it a promising high-performance bonding material for superhard abrasive tools.