Radiation induced grafting of amphiphilic double poly(ionic liquid) copolymer onto silica surface for the removal of ReO4- as analogue of TcO4-

被引:0
|
作者
Zhang, Na [1 ]
Yang, Miao [1 ]
Zhang, Manman [2 ]
Du, Jifu [3 ]
Bao, Qiburi [1 ]
Zhao, Long [2 ]
Dong, Zhen [1 ]
机构
[1] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Wuhan 430070, Peoples R China
[2] Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Peoples R China
[3] Hubei Univ Sci & Technol, Sch Nucl Technol & Chem & Biol, Xianning 437100, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
ReO4-; TcO4-; Poly(ionic liquid); Silica; Radiation grafting; Removal; COVALENT ORGANIC FRAMEWORK; IONIC LIQUID; PERRHENATE; ADSORPTION; EFFICIENT; WASTE; ANION; IMMOBILIZATION; SELECTIVITY; SORPTION;
D O I
10.1007/s10967-023-08849-w
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Amphiphilic double poly(imidazole ionic liquid) grafted silica (SMIL-n) was prepared by radiation grafting of hydrophilic 1-vinyl-3-ethylimidazolium bromide and hydrophobic 1-vinyl-3-octylimidazolium bromide at different ratio onto silica. The adsorption behavior of SMIL-n was investigated. The adsorption equilibrium could reach less than 45 min, and their adsorption capacity were 152-171 mg/g obtained from Langmuir model. The selectivity of SMIL-n to ReO4- increased with the increasing content of hydrophobic ionic liquid. SMIL-n displayed good reusability, excellent acid resistance and irradiation resistance. Particularly, SMIL-n showed promising for ReO4- uptake from simulated contaminated Beishan groundwater and radioactive wastewater.
引用
收藏
页码:1869 / 1881
页数:13
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