Lauric Acid-based Polyol Esters as Potential Bio-based Lubricants for Diesel Fuel

被引:0
|
作者
Pucko, I. [1 ]
Crnjac, K. [1 ]
Faraguna, F. [1 ]
机构
[1] Univ Zagreb, Fac Chem Engn & Technol, Petr & Petrochem Dept, Trg Marka Marulica 19, Zagreb 10000, Croatia
关键词
lubricants; polyols; diesel fuel; lauric acid; esters; friction; TRIMETHYLOLPROPANE ESTERS; ENZYMATIC PRODUCTION; IMMOBILIZED LIPASE; VEGETABLE-OILS; BIOLUBRICANTS; ESTERIFICATION;
D O I
10.15255/CABEQ.2023.2185
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
In this paper, lubricants based on lauric acid and different polyols neopentyl glycol (NPG), trimethylolpropane (TMP) and pentaerythritol (PE) - were synthesized. After purification, their purity of > 97 mol% was confirmed by infrared spectroscopy and proton nuclear magnetic resonance. Synthesized lubricants 100 to 5000 ppm formulations with diesel showed similar density, kinematic viscosity, and low-temperature behavior to diesel according to standard tests, meaning that they can be used in current diesel engines. They have improved the lubricity of the formulations, as confirmed by a lower coefficient of friction, and an almost 50 % improvement in wear scar diameter (according to EN 12156-1).
引用
收藏
页码:143 / 151
页数:9
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