Ablation behavior of C/C-Zr1-xHfxC-SiC composites under an oxyacetylene flame at above 2500 °C

In order to enhance ablation resistance of C/C composites, Zr1-xHfxC and SiC were intro-duced into C/C composites, and ablation behavior of the composites was studied. In the composites (CHZS), HfC and ZrC produced a solid solution, and solid solubility of HfC in ZrC was 0.4, which indicated that the solid solution was defined to be Zr0.6Hf0.4C. Compared with C/C-ZrC-SiC composites (CZS), CHZS possessed a better ablation resistance. During ablation of CHZS, Zr0.6Hf0.4C is oxidized to produce HfO2 and ZrO2, and HfO2 particles played a pinning effect, which fixed molten oxide coating. Moreover, due to low CTE of HfO2 and decreasing content of ZrO2, there was a smaller thermal stress and its distribu-tion area on CHZS ablation surface, thus thermal stress corrosion was weakened to strengthen integrity of oxide coating. In this case, a complete and continuous HfO2-ZrO2 coating was formed on CHZS surface, which could resist oxygen diffusion and reduce oxidation rate of the composites.& COPY; 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).