Experimental and kinetic study on JP-10/air autoignition and the effect of NO2 at high temperatures

Ignition delay times of JP-10 in air and the vitiation effect of NO2 on JP-10 autoignition at high temperatures were investigated behind reflected shock waves. The experiments were carried out at pressures of 2 and 10 atm, temperatures between 900 and 1460 K, fuel lean and stoichiometric conditions with and without 1.0 % NO2. The experimental results show that the ignition delay times of JP-10/air decrease with the increase of pressure or the decrease of equivalence ratio. The effect of adding 1.0 % NO2 is pressure dependence. At 10 atm, the addition of NO2 promotes the ignition of fuel, which shortens the ignition delay time. At 2 atm, the addition of 1.0 % NO2 inhibits the ignition of JP-10, which prolongs the ignition delay time. A chemical kinetic mechanism of JP-10/ NO2 consisting of 290 species and 1768 reactions was developed by extending from a C0-C5 alkane and a cyclopentene sub-mechanism. The proposed mechanism has been well validated by ignition delay times, laminar flame speeds and species concentration profiles from literature. To further investigate the autoignition of JP-10 and the vitiation effect of NO2, kinetics analyses including reaction pathways and sensitivity coefficients were performed by the developed mechanism. The main consumption pathways of JP-10 in air are H-abstraction reactions from JP-10 by HO2 radicals. With 1.0 % NO2 vitiation, the addition of NO2 has a strong effect on JP-10 consumption via the H-abstraction pathway JP-10 + NO2 = C10H15 + HONO, which further affects the auto -ignition of JP-10.