Lithium extraction from salt lake brines with high magnesium/lithium ratio: a review

被引：56

作者：

Zhu, Rong ^{[1
,2
]}

Wang, Shixin ^{[1
,2
]}

Srinivasakannan, C. ^{[3
]}

Li, Shiwei ^{[1
,2
]}

Yin, Shaohua ^{[1
,2
]}

Zhang, Libo ^{[1
,2
]}

Jiang, Xiaobin ^{[4
]}

Zhou, Guoli ^{[5
]}

Zhang, Ning ^{[4
]}

机构：

[1] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Yunnan, Peoples R China

[2] Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cle, Kunming 650093, Yunnan, Peoples R China

[3] Khalifa Univ Sci & Technol, Chem Engn Dept, Abu Dhabi, U Arab Emirates

[4] Dalian Univ Technol, Frontier Sci Ctr Smart Mat, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116023, Peoples R China

[5] Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

ENVIRONMENTAL CHEMISTRY LETTERS | 2023年 / 21卷 / 03期

关键词：

Sustainable development; Salt lake brines; Extraction and separation; Lithium resources; METHYL ISOBUTYL KETONE; TRIBUTYL-PHOSPHATE; ION BATTERIES; LI EXTRACTION; NANOFILTRATION; ADSORPTION; SEPARATION; MEMBRANE; RECOVERY; ELECTRODIALYSIS;

D O I：

10.1007/s10311-023-01571-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The demand for lithium is growing rapidly with the increase in electric vehicles, batteries and electronic equipments. Lithium can be extracted from brines, yet the separation of lithium ions Li+ from magnesium ions Mg2+ is challenging at high Mg/Li ratios. Here, we review methods to extract lithium from brines, such as extraction, adsorption, nanofiltration, selective electrodialysis and electrochemical intercalation/de-intercalation, with focus on the selective separation of lithium at high Mg/Li ratios. Extraction can be done with organic solvents and ionic liquids. Adsorption is performed with aluminum-, manganese- and titanate-based adsorbents.

引用

页码：1611 / 1626

页数：16

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