Directed C8-H allylation of quinoline N-oxides with vinylcyclopropanes via sequential C-H/C-C activation

被引：11
|
作者：
Mandal, Santu [1 ]
Karjee, Pallab [1 ]
Saha, Sharajit [1 ]
Punniyamurthy, Tharmalingam [1 ]
机构：
[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 19期
关键词：
D O I：
10.1039/d2cc06646g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Rh(iii)-catalyzed C8-allylation of quinoline N-oxides has been accomplished using vinylcyclopropanes as an allyl source with excellent diastereoselectivity at room temperature. The C-H/C-C activation, substrate scope and natural product mutation are the important practical features.
引用
收藏
页码：2823 / 2826
页数：4
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