A new cobalt(<sc>ii</sc>)-lithium(<sc>i</sc>) carboxylate complex with an N,O-donor mono-iminoacenaphthenone ligand: synthesis, structure and magnetic behavior

被引：1

作者：

Yambulatov, Dmitriy S. ^{[1
]}

Nikolaevskii, Stanislav A. ^{[1
]}

Lukoyanov, Anton N. ^{[2
]}

Shmelev, Maxim A. ^{[1
]}

Voronina, Julia K. ^{[1
]}

Babeshkin, Konstantin A. ^{[1
]}

Matiukhina, Anna K. ^{[1
]}

Efimov, Nikolay N. ^{[1
]}

Kiskin, Mikhail A. ^{[1
]}

Eremenko, Igor L. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, 31 Leninsky Prosp, Moscow 119991, Russia

[2] Russian Acad Sci, Razuvaev Inst Organometall Chem, Tropinina 49, Nizhnii Novgorod 603950, Russia

来源：

NEW JOURNAL OF CHEMISTRY | 2023年 / 47卷 / 42期

基金：

俄罗斯科学基金会;

关键词：

D O I：

10.1039/d3nj04144a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new carboxylate complex [Co2Li2(Piv)(6)(L)(2)]-CH3CN (1) (Piv is the anion of pivalic acid) has been synthesized and structurally characterized. According to ac magnetic measurements, compound 1 exhibits a field induced slow magnetic relaxation, which is approximated by a combination of Raman and direct mechanisms. These data are confirmed by ab initio calculations indicating easy-plane anisotropy of Co(ii) ions in the complex.

引用

页码：19362 / 19366

页数：5

共 44 条

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