Silver-catalyzed oxidative alkylation/alkynylation of 1,4-enynyl-3-ols with alkylbromides through radical 1,2-alkynyl migration

被引：0

作者：

Chen, De ^{[1
]}

Zhang, Nianqi ^{[1
]}

Liang, Qiuju ^{[2
,3
]}

Deng, Wei ^{[1
]}

Xiao, Zhiyi ^{[2
]}

Dong, Wanrong ^{[1
]}

Xiang, Jiannan ^{[1
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, Adv Catalyt Engn Res Ctr, Minist Educ, Changsha 410082, Hunan, Peoples R China

[2] Wujo High Tech Mat Co Ltd, Hunan Engn Technol Ctr Photog Mat 2022TP2027, Loudi 417000, Hunan, Peoples R China

[3] China Tobacco Hunan Ind Co Ltd, Technol Ctr, Laodong Mid Rd 426, Changsha 410014, Hunan, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2024年 / 186卷

关键词：

12-Alkynyl migration; Silver-catalysis; 1,4-Enynyl-3-ols; Alkylbrmodes; Alkynylation/alkylation; ALLYLIC ALCOHOLS; ALKENES; FUNCTIONALIZATION; DIFUNCTIONALIZATION; CARBON;

D O I：

10.1016/j.catcom.2023.106824

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, we have described a novel reaction between 1,4-enynyl-3-ols and alkyl bromides. The reaction was carried out in the presence of Ag2O, following a free radical 1,2-alkynyl migration pathway, which was confirmed through control experiments. This methodology offers several advantages, including high efficiency and a wide range of applicable substrates.

引用

页数：5

共 18 条

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