Fabrication of polydopamine/polyaniline decorated multiwalled carbon nanotube composite as multifunctional electrode material for supercapacitor applications

被引:14
|
作者
Elanthamilan, Elaiyappillai [1 ,2 ]
Ganeshkumar, Arumugam [3 ,4 ]
Wang, Sea-Fue [1 ]
Rajaram, Rajendran [5 ]
Thriambakeshwar, Selvakumar [2 ]
Velusamy, Mathiyazhagan [2 ]
机构
[1] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, 1 Chung Hsiao East Rd,Sect 3, Taipei 106, Taiwan
[2] Affiliated Bharathidasan Univ, Bishop Heber Coll Autonomous, Dept Chem, Trichy 620017, Tamil Nadu, India
[3] Sao Paulo State Univ, UNESP, ICT, Dept Microbiol & Immunol, Sao Jose Dos Campose, Brazil
[4] Saveetha Sch Engn, Dept Mat Phys, Chennai 602105, Tamilnadu, India
[5] Bharathidasan Univ, Dept Marine Sci, DNA Barcoding & Marine Genom Lab, Trichy, India
关键词
Polydopamine; Polyaniline; Carbon nanotubes; Supercapacitors; Specific capacitance; ULTRATHIN NICO2O4 NANOSHEETS; HIGH-PERFORMANCE; FACILE SYNTHESIS; GRAPHENE OXIDE; DOPED CARBON; HYBRID; NANOPARTICLES; POLYANILINE; TEMPLATE; HYDROGEN;
D O I
10.1016/j.synthmet.2023.117423
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this article, we report polydopamine/polyaniline decorated CNT composite (PDA/PANI@CNT) via an in situ -polymerization route for hybrid supercapacitor application. The structural and morphological features of the as -synthesized PDA, PDA/PANI and PDA/PANI@CNT composite were proved using various physicochemical techniques such as FT-IR, Raman, XRD, FESEM, TEM, BET and XPS analysis. The supercapacitive performance of the electrode fabricated using PDA/PANI@CNT was further evaluated by CV, GCD and electrochemical impedance spectroscopy (EIS) analyses in aq. 1 M KOH. It is worth mentioning that the perfectly interconnected PDA/PANI@CNT composite delivered the specific capacitance of 970 F/g at 5 mV/s and 91 % of capacitance retention value after 6000 GCD cycles at 3 A/g and subsequently implied that PDA/PANI@CNT composite can be applied as electrode material in supercapacitors. Meanwhile, the biocidal potency of the PDA, PDA/PANI and PDA/PANI@CNT were evaluated and PDA/PANI@CNT was found to be better one comparison with PDA and PDA/PANI. This assay provided evidence that CNT can act as a synergetic one to enhance the biological property of the PDA/PANI.
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页数:10
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