Catalytic Conversion of Levulinic Acid into 2-Methyltetrahydrofuran: A Review

被引:5
|
作者
Gundekari, Sreedhar [1 ]
Karmee, Sanjib Kumar [2 ]
机构
[1] KL Deemed Univ, Koneru Lakshmaiah Educ Fdn, Dept Engn Chem, Moinabad Chilkur Rd, Aziznagar 500075, Telangana, India
[2] Odisha Renewable Energy Res Inst ORERI, Subarnapur 767018, Odisha, India
来源
MOLECULES | 2024年 / 29卷 / 01期
关键词
biomass; furanic molecules; levulinic acid; 2-methyltetrahydrofuran; hydrogenation; GEL-PERMEATION CHROMATOGRAPHY; GAMMA-VALEROLACTONE; 2-METHYL TETRAHYDROFURAN; SOLVENT ELECTROLYTES; PLATFORM CHEMICALS; HYDROGEN SOURCE; EFFICIENT; TRANSFORMATION; EXTRACTION; 1,4-PENTANEDIOL;
D O I
10.3390/molecules29010242
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Biomass-derived furanics play a pivotal role in chemical industries, with 2-methyltetrahydrofuran (2-MTHF), a hydrogenated product of levulinic acid (LA), being particularly significant. 2-MTHF finds valuable applications in the fuel, polymer, and chemical sectors, serving as a key component in P-series biofuel and acknowledged as a renewable solvent for various chemical processes. Numerous research groups have explored catalytic systems to efficiently and selectively convert LA to 2-MTHF, using diverse metal-supported catalysts in different solvents under batch or continuous process conditions. This comprehensive review delves into the impact of metal-supported catalysts, encompassing co-metals and co-catalysts, on the synthesis of 2-MTHF from LA. The article also elucidates the influence of different reaction parameters, such as temperature, type and quantity of hydrogen source, and time. Furthermore, the review provides insights into reaction mechanisms for all documented catalytic systems.
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页数:23
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