An energy-efficient and cleaner production of hydrogen by steam reforming of glycerol using Aspen Plus

被引:6
|
作者
Haider, Md Alquma [1 ]
Chaturvedi, Nitin Dutt [1 ]
机构
[1] Indian Inst Technol Patna, Dept Chem & Biochem Engn, Patna 801106, Bihar, India
关键词
Hydrogen; Glycerol; Steam reforming; Stoichiometry; Thermodynamics; BIODIESEL BY-PRODUCT; RENEWABLE HYDROGEN; THERMODYNAMIC ANALYSIS; GENERATION; CATALYSTS; SYNGAS; CHALLENGES; OPTIONS;
D O I
10.1016/j.ijhydene.2023.09.089
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen (H2) is produced in an efficient and sustainable manner using steam reforming of glycerol in this work. Two models are used to provide anticipation about how efficiently H2 can be produced: Model 1, a stoichiometric model, and Model 2, a thermodynamic model. Model 1 helps determine the water/glycerol molar input ratio and reaction pathway. The thermodynamic feasibility of Model 1 is examined using Model 2, which then determines the optimum conditions for maximal H2 generation. Model 2 produced 1275 kmol/h of H2 with an H2 mole fraction of 0.49 at 658 degrees C and 1 atm of pressure. The reactor's net heat load is greatly reduced through heat integration in this study. The energy required is reduced by 29.5% as compared to when no heat integration is used. The process of separating and
引用
收藏
页码:1311 / 1320
页数:10
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