An improved cobalt-catalysed alkoxycarbonylation of olefins using secondary phosphine oxide promotors

被引：6

作者：

Huang, Weiheng ^{[1
]}

Jackstell, Ralf ^{[1
]}

Spannenberg, Anke ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Leibniz Inst Katalyse e V, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2023年 / 13卷 / 08期

基金：

欧盟地平线“2020”;

关键词：

NONNOBLE METAL-CATALYSTS; LEVULINIC ACID; HYDROFORMYLATION; CARBONYL; WATER; BASES;

D O I：

10.1039/d3cy00066d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In general, cobalt-catalysed carbonylations of olefins require high carbon monoxide (CO) pressure and high temperature to proceed efficiently. In contrast, the presence of secondary phosphine oxide (SPO) promotors allows the formation of esters from alkenes and alcohols under comparably milder reaction conditions (typically 120 degrees C, 40 bar). The influence of several types of SPOs was investigated and kinetic studies showed a significant acceleration of the formation of the active cobalt catalyst in the presence of simple diphenylphosphine oxide.

引用

页码：2475 / 2479

页数：5

共 25 条

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