N6-ferrocenylcarbonyl derivatives of sydnone imines: synthesis, modification, growth-regulating and antidote against herbicide "Zinger" activities

被引：2

作者：

Kalganova, Natalia V. ^{[1
]}

Frolova, Natalia G. ^{[1
]}

Godovikov, Ivan A. ^{[1
]}

Smol'yakov, Alexander F. ^{[1
]}

Lapshin, Dmitriy A. ^{[1
]}

Cherepanov, Iliya A. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, INEOS, Vavilova St 28,Bld 1, Moscow 119334, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2024年 / 1005卷

基金：

俄罗斯科学基金会;

关键词：

Ferrocene; Sydnone imines; Organolithium compounds; Plant growth regulators; Herbicide antidotes; CHEMISTRY; POLYMERS;

D O I：

10.1016/j.jorganchem.2023.122975

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first N6-ferrocenylcarbonyl derivatives of sydnone imines were synthesized by the reaction of sydnone imine hydrochlorides with ferrocenoyl chloride. The possibility of deprotonation of C(4)-H of the oxadiazole ring in N6- ferrocenylcarbonyl derivatives of sydnone imines under the action of n-butyllithium was demonstrated. The reactivity of 4-lithio derivatives was studied and methods of their functionalization were developed. In vege-tation experiments on corn seedlings, the growth-regulating properties and antidote activity against Metsulfuron-Methyl (Zinger WP) herbicide of the synthesized ferrocenyl containing sydnone imine derivatives were studied.

引用

页数：9

共 14 条

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Cherepanov, I. A.
RUSSIAN CHEMICAL BULLETIN, 2023, 72 (07) : 1688 - 1700
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N. V. Kalganova
A. F. Smolyakov
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Russian Chemical Bulletin, 2023, 72 : 1688 - 1700
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VASSILEV, GN
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