Tuning the electrochemical performance of binary CuFe2O4 incorporated by ZnO nanoparticles for high performance hybrid supercapacitors

被引:7
|
作者
Rushmittha, J. J. [1 ,3 ]
Radhika, S. [2 ,3 ]
Maheshwaran, G. [4 ]
Padma, C. M. [1 ,3 ]
机构
[1] Womens Christian Coll, Dept Phys & Res Ctr, Nagercoil, Tamil Nadu, India
[2] Pioneer Kumaraswamy Coll, Dept Phys, Nagercoil, Tamil Nadu, India
[3] Manonmaniam Sundaranar Univ, Tirunelveli 627012, Tamil Nadu, India
[4] SRM Univ, Dept Chem, Amaravati 522240, Andhra Pradesh, India
关键词
Copper ferrite; Supercapacitor; Hybrid device; Energy density; METAL OXIDES NANOSHEETS; HIGH-ENERGY DENSITY; COMPOSITE;
D O I
10.1016/j.inoche.2023.111728
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Developing magnetic nanomaterials with exceptional electrochemical activities is the cutting edge in the fields of advanced supercapacitor applications. Herein, the binary copper ferrite nanocomposite has been prepared by a cost-effective co-precipitation method and their electrochemical activity has been enhanced by incorporating the different molar concentrations of zinc oxide nanoparticles in its lattice. Zinc oxide incorporated copper ferrite nanocomposite (Zn-CFO-1 NC) electrode delivers the maximum specific capacity of about 409.7 C/g at the sweep rate of 10 mV/s. The charge storage mechanism has been revealed by the Trasatti method, delivering the total, outer, and inner capacities of Zn-CFO-1 of 826.4, 41.0, and 784.4 C/g respectively along with the diffusion and capacitive contributions of 95% and 5% correspondingly. The supercapacitor device (SCD) has been fabricated by Zn-CFO-1 as cathode and activated carbon (AC) anode in 3 M KOH as an electrolytic medium, which provides the maximum energy density of about 17.8 Wh/kg and their maximum power density of about 3125 W/kg.
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页数:10
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