Fabrication of Nd2S3 based rGO nanohybrid via hydrothermal route and evaluation of capacitive features toward supercapacitor application

被引:39
|
作者
Abdullah, Muhammad [1 ]
Alanazi, Meznah M. [2 ]
Abdelmohsen, Shaimaa A. M. [2 ]
Alahmari, Saeed D. [3 ]
Aman, Salma [4 ]
Sadaf, Asma [5 ]
Al-Sehemi, Abdullah G. [6 ,7 ]
Henaish, A. M. A. [8 ,9 ]
Ahmad, Zubair [10 ]
Farid, Hafiz Muhammad Tahir [11 ]
机构
[1] Govt Coll Univ Lahore, Dept Chem, Lahore 54000, Pakistan
[2] Princess Nourah bint Abdulrahman Univ, Coll Sci, Dept Phys, POB 84428, Riyadh 11671, Saudi Arabia
[3] Jazan Univ, Fac Sci, Dept Chem, POB 2097, Riyadh 45142, Saudi Arabia
[4] Khwaja Fareed Univ Engn & Informat Technol, Inst Phys, Abu Dhabi Rd, Rahim Yar Khan 64200, Pakistan
[5] Punjab Tianjin Univ Technol Lahore, Lahore 54000, Pakistan
[6] King Khalid Univ, Res Ctr Adv Mat Sci RCAMS, Abha 61413, Saudi Arabia
[7] King Khalid Univ, Coll Sci, Dept Chem, Abha 61413, Saudi Arabia
[8] Tanta Univ, Fac Sci, Phys Dept, Tanta 31527, Egypt
[9] Ural Fed Univ, NANOTECH Ctr, Ekaterinburg 620002, Russia
[10] Yeungnam Univ, Sch Chem Engn, 280 Daehak Ro, Gyongsan 38541, Gyeongbuk, South Korea
[11] Govt Grad Coll Taunsa Sharif, Dept Phys, Taunsa Sharif 32100, Pakistan
关键词
Hydrothermal approach; Supercapacitor applications; Rare earth metal sulphide; KOH electrolyte; ELECTRODE MATERIALS; ENERGY-CONVERSION; FACILE SYNTHESIS; GRAPHENE; NANOCOMPOSITE; COMPOSITES; NANOPARTICLES; NANOSPHERES; STORAGE;
D O I
10.1016/j.mseb.2024.117207
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The two-dimensional metal sulphide acts as potent electrodes for supercapacitors; instead, they require further cycle stability and performance rate improvements before they can be used in real -world applications. Improved supercapacitor efficacy can be achieved by developing binder -free and hierarchical carbon nanohybrid electrode materials. Herein, we report the fabrication of a binder -free Nd2S3-based rGO nanohybrid electrode via the hydrothermal route for energy -saving equipment. Several analytical tools were used to determine the physiochemical features of the all -synthesized electrode materials. Several electrochemical tests, such as cyclic voltammetry and galvanostatic charge-discharge (GCD), were utilized to determine the pseudocapacitive nature of fabricated materials. The Cs from GCD of Nd2S3/reduced GO nanohybrid (782.46 F g-1) was greater than Nd2S3 (332.69 F g-1) and reduced GO (470.18 F g-1). Furthermore, the Nd2S3/reduced GO electrode shows excellent cyclic stability with a rate capability of 90 % over 5000th cycles. It facilitates the perfect connection for fast electrolyte ion diffusion between the electrolyte and electrode surface. Incorporating rGO into rare earth metal sulphide significantly enhances the capacitive characteristics of the electrode due to providing a larger surface area and enriching active zones. These findings suggest that supercapacitors may be constructed using binderfree Nd2S3/reduced GO electrodes, resulting in better electrochemical characteristics.
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页数:10
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