Self-healing and shape-memory polymers based on cellulose acetate matrix

The creation of self-healing polymers with superior strength and stretchability from biodegradable materials is attracting increasing attention. In this study, we synthesized new biomass-derived cellulose acetate (CA) derivatives by ring-opening graft polymerization of delta-valerolactone followed by the introduction of ureidopyrimidinone (Upy) groups in the polymer side chains. Due to the semicrystalline aliphatic characteristics of the side chain poly(delta-valerolactone) (PVL) and quadruple hydrogen bonds formed by the Upy groups, the stretchability of the resulting polymers was significantly enhanced. Moreover, the shape memory ability and self-healing property (58.3% of self-healing efficiency) were successfully imparted to the polymer. This study demonstrates the great significance of using biomass sources to create self-healing polymers. [GRAPHICAL ABSTRACT]