Characterization and Comparison of WO3/WO3-MoO3 and TiO2/TiO2-ZnO Nanostructures for Photoelectrocatalytic Degradation of the Pesticide Imazalil

被引:0
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作者
Cifre-Herrando, Mireia [1 ]
Rosello-Marquez, Gemma [1 ]
Navarro-Gazquez, Pedro Jose [1 ]
Munoz-Portero, Maria Jose [1 ]
Blasco-Tamarit, Encarnacion [1 ]
Garcia-Anton, Jose [1 ]
机构
[1] Univ Politecn Valencia, Inst Univ Segur Ind Radiofis & Medioambiental ISIR, Ingn Electroquim & Corros IEC, C Camino Vera S-n, Valencia 46022, Spain
关键词
nanostructures; hybrid nanostructures; WO3; TiO2; water splitting; emerging contaminants; TIO2 NANOTUBE ARRAYS; ENDOCRINE-DISRUPTING COMPOUNDS; NANOPOROUS WO3 FILM; PHOTOCATALYTIC DEGRADATION; WATER; REMOVAL; ZNO; OPTIMIZATION; PERFORMANCE; PHARMACEUTICALS;
D O I
10.3390/nano13182584
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tungsten oxide (WO3) and zinc oxide (ZnO) are n-type semiconductors with numerous applications in photocatalysis. The objective of this study was to synthesize and characterize different types of nanostructures (WO3, WO3-Mo, TiO2, and TiO2-ZnO) for a comparison of hybrid and pure nanostructures to use them as a photoanodes for photoelectrocatalytic degradation of emerging contaminants. With the aim of comparing the properties of both samples, field emission scanning electron microscopy (FE-SEM) and confocal laser-Raman spectroscopy were used to study the morphology, composition, and crystallinity, respectively. Electrochemical impedances, Mott-Schottky, and water splitting measurements were performed to compare the photoelectrochemical properties of photoanodes. Finally, the photoelectrocatalytic degradation of the pesticide Imazalil was carried out with the best optimized nanostructure (TiO2-ZnO).
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页数:23
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