Determination of polycyclic aromatic compounds from a solid-waste dumpsite fire smoke using hollow-fibre membranes sampling coupled to gas chromatography and mass spectrometry

Improperly managed solidwaste dumpsites are a potential time bomb as these can pose serious deleterious hazards to the neighbouring communities. This was the case in Maseru Lesotho one warm afternoon when the dumpsite caught fire with no clear human activity, producing dark smoke that covered the residential area around the site. The current study reports the use of simple passive samplers composed of polypropylene hollow fibre membranes impregnated with dodecane for screening of polycyclic aromatic hydrocarbons in this dumpsite fire smoke. The fibres were suspended at different sampling locations at the dumpsite and inside and outside the surrounding households and left there to sample for 6 hours after which 1-cm pieces were placed in headspace vials for desorption and further analysed by gas chromatography and mass spectrometry. The detected compounds were annotated using the NIST 2017 MS library comparison and the following compounds were found: acenaphthene, naphthalene, biphenylene, flourene, phenanthrene, flouranthene, benzoflouranthene, pyrene and clopentapyrene. Given there were no standards available, the compounds could not be quantified. Nonetheless, the results demonstrated the potential for a simple hollow-fibre liquidphase microextraction technique for use in the screening of PAHs in smoke. Most importantly, they reflect the importance of negative impact of the dumpsite smoke being so rich in these compounds that have been classified as carcinogens.