Electrochemical conversion of biomass-derived aldehydes into fine chemicals and hydrogen: A review

被引：21

作者：

Theerthagiri, Jayaraman ^{[1
]}

Karuppasamy, K. ^{[2
]}

Park, Juhyeon ^{[1
]}

Rahamathulla, Nihila ^{[3
]}

Kumari, M. L. Aruna ^{[4
]}

Souza, Marcielli K. R. ^{[5
]}

Cardoso, Eduardo S. F. ^{[5
]}

Murthy, Arun Prasad ^{[3
]}

Maia, Gilberto ^{[5
]}

Kim, Hyun-Seok ^{[2
]}

Choi, Myong Yong ^{[1
]}

机构：

[1] Gyeongsang Natl Univ, Core Facil Ctr Photochem & Nanomat, Res Inst Nat Sci, Dept Chem BK21 Four, Jinju 52828, South Korea

[2] Dongguk Univ Seoul, Div Elect & Elect Engn, Seoul 04620, South Korea

[3] Vellore Inst Technol, Sch Adv Sci, Dept Chem, Vellore 632014, Tamil Nadu, India

[4] Oxford Coll Sci, Dept Chem, Bengaluru 560102, Karnataka, India

[5] Univ Fed Mato Grosso do Sul, Inst Chem, Av Senador Filinto Muller 1555, BR-79074460 Campo Grande, MS, Brazil

来源：

ENVIRONMENTAL CHEMISTRY LETTERS | 2023年 / 21卷 / 03期

基金：

新加坡国家研究基金会;

关键词：

Biomass-derived aldehydes; Furfural; 5-Hydroxymethylfurfural; Electrochemical oxidization; Hydrogenation; Hybrid water electrolyzer; Value-added chemicals; Hydrogen fuel; PHASE SELECTIVE HYDROGENATION; SINGLE-REACTOR PROCESS; FURFURYL ALCOHOL; BIO-OIL; HYDROTHERMAL CARBONIZATION; EFFICIENT CONVERSION; OXIDATION; ACID; PD; PYROLYSIS;

D O I：

10.1007/s10311-022-01543-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The decrease in fossil fuel usage and the projected 28% increase in the global energy demand by 2040 are calling for advanced methods to convert modern biomass into fine chemicals. For instance, biomass-derived aldehydes appear as promising substitutes for the chemical and fuel industries. Here, we review electrochemical upgrading of furfural and 5-hydroxymethylfurfural with a focus on catalysis and selectivity mechanisms. We also present hybrid water electrolysis systems for production of hydrogen and chemicals. We discuss electrochemical oxidation or hydrogenation of furfural and 5-hydroxymethylfurfural using metal oxides, noble metals, transition metal nanoparticles and alloys, and nonoxides. We compare electrochemical processes with combustion, chemical, thermochemical, and biochemical processes for biomass conversion.

引用

页码：1555 / 1583

页数：29

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